Which of these is an ancient eye cosmetic, traditionally made by grinding stibnite?

I wish my in-laws had used it on my wife as a baby. She gives me the evil eye quite often.

I thought this had been banned in cosmetics for being the cause of a lot of eye problems .no mention in the answer though.

Since the rest aren’t eye makeup…

I remember my aunt burning a candle under a saucer and using the soot as eyeliner, when I was a child in the 60s.